ChemInform Abstract: Siloxy-(2,3)Wittig Rearrangement: A New Method for Diastereoselective Preparations of 1,2-Diol Systems

Autor:	Ei-ichi Nakai, Takeshi Nakai
Rok vydání:	1989
Předmět:	chemistry.chemical_compound Chemistry Stereochemistry Diol Wittig reaction General Medicine 2 3-Wittig rearrangement
Zdroj:	ChemInform. 20
ISSN:	0931-7597
DOI:	10.1002/chin.198923082
Popis:	A novel [2,3]Wittig variant, termed “siloxy-[2,3]Wittig rearrangement”, has been developed which provides the half-silylated 1,2-diol systems with a high anti-diastereoselectivity. The unusual anti-selectivity is discussed on mechanistic grounds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cea0f6f15d5865eaded6a43ebdbfecda https://doi.org/10.1002/chin.198923082 Zobrazit plný text záznamu Plný text