A novel 2D layered network based on 13-vanadomanganate(IV): K3(HABOB)4[MnV13O38]·9H2O (ABOB=N-amidino-4-morpholincarboxamidine)

Autor:	Shuxia Liu, Enbo Wang, Ninghai Hu, Dehui Li, Lin-Hua Xie, Hengqing Jia, Chunyan Sun
Rok vydání:	2005
Předmět:	Structure analysis Analytical chemistry chemistry.chemical_element Manganese Nuclear magnetic resonance spectroscopy Electrochemistry Inorganic Chemistry Crystallography chemistry Polyoxometalate Atom Materials Chemistry Physical and Theoretical Chemistry Stoichiometry
Zdroj:	Inorganic Chemistry Communications. 8:433-436
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2005.02.002
Popis:	A novel organic–inorganic hybrid based on heteropolyvanadate with manganese central atom and unusual 1:13 stoichiometry, K 3 (HABOB) 4 [MnV 13 O 38 ] · 9H 2 O ( 1) (ABOB = N -amidino-4-morpholincarboxamidine) was prepared. X-ray structure analysis has revealed that compound 1 exhibits an interesting 2D layered network with a 1D tunnel. The 51 V NMR spectrum indicates that the heteropolyanion with C 2v symmetry, [MnV 13 O 38 ] 7− , is present in solution. And electrochemical behaviors of compound 1 have been investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ce694efddd51de74117e7676f4e95943 https://doi.org/10.1016/j.inoche.2005.02.002 Zobrazit plný text záznamu Full Text from ScienceDirect