N-doped C-encapsulated scale-like yolk-shell frame assembled by expanded planes few-layer MoSe2 for enhanced performance in sodium-ion batteries
| Autor: | Beihong Liu, Xiaofei Yang, Hong Guo, Lin Wang, Timur Borjigin, Mengfang Liang, Yuhao Zhang, Xueliang Sun, Hui Liu |
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| Rok vydání: | 2018 |
| Předmět: |
Pressing
Materials science Renewable Energy Sustainability and the Environment Doping Shell (structure) chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences 0104 chemical sciences Anode Crystal Chemical engineering chemistry General Materials Science Electrical and Electronic Engineering 0210 nano-technology Layer (electronics) Carbon |
| Zdroj: | Nano Energy. 51:639-648 |
| ISSN: | 2211-2855 |
| DOI: | 10.1016/j.nanoen.2018.07.021 |
| Popis: | To meet the pressing needs of fast development of energy and environmental science, sodium ion batteries (SIBs) are considered as the promising novel generation of power storage system, due to abundant reserves and low price of sodium sources. In this work, N-doped C-encapsulated scale-like yolk-shell structured MoSe2-C materials assembled by expanded (002) planes few-layer MoSe2 nanosheets are successfully synthesized by a facile general strategy. The few-layer crystal fringes are no more than 4 layers. Notably, the interlayer spacing of (002) planes is expanded to 1.15 nm, which is larger than its intrinsic value of pristine MoSe2 (0.64 nm). Particularly, the few-layer nanosheets with expanded (002) planes are spaced-restricted growing in the inner wall and the surface of hollow carbon frame and form scale-like yolk-shell hybrid MoSe2-C structure. When evaluated as anode for SIBs, the MoSe2-C materials show ultra-long cycling life, maintaining 378 mA h g−1 over 1000 cycles at 3 A g−1. It also exhibits outstanding rate capability and the Coulombic efficiencies for all the rate performance reaching more than 98.3% except the first one. The expanded (002) planes, 2D fewer-layer nanosheets and unique N-doped C-encapsulated scale-like yolk-shell frame are responsible for the enhanced electrochemical performance. |
| Databáze: | OpenAIRE |
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