Axial Crystal Fields in the Ionic Model
| Autor: | R. L. Carlin, T. S. Piper |
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| Rok vydání: | 1960 |
| Předmět: | |
| Zdroj: | The Journal of Chemical Physics. 33:1208-1211 |
| ISSN: | 1089-7690 0021-9606 |
| DOI: | 10.1063/1.1731358 |
| Popis: | Expressions for the axial components of crystal fields of tetragonal, trigonal, and cylindrical symmetry are developed in terms of the parameters Ds and Dt. These parameters are calculated in the ionic model using Hartree‐Fock 3d radial wave functions. The calculated parameters are compared to experimental values obtained from the spectra of V(III) in Al2O3 and Co(II) in CoO. Tentative assignments of the bands in the spectrum of (C5H5)2Ni are made. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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