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In light of the controversial discussion of the interfacial structure of water on metal surfaces, adsorption of D 2 O on Ru(0 0 1) is investigated using sum-frequency generation vibrational spectroscopy. In contrast to a recent theoretical study claiming partial dissociation of the first bilayer of water on Ru(0 0 1) [Science 295 (2002) 99], clear spectroscopic evidence is found that the adsorbed molecules remain intact. In the context of all experimental data available, a bilayer structure where every second water molecule exhibits a hydrogen–metal bond with a comparably large, proton-disordered unit cell seems most plausible. |
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