{[Ir3(cod)3(μ3-S)2](μ3-S)SnCl}2 – a ternary Ir–Sn–S cluster with the iridium atoms in three different chemical environments

Autor:	Bastian Weinert, Eliza Leusmann, Eugenie Geringer, Stefanie Dehnen
Rok vydání:	2016
Předmět:	Quantum chemical 010405 organic chemistry Chemistry Inorganic chemistry chemistry.chemical_element Electronic structure 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Crystallography Cluster (physics) Iridium Ternary operation Topology (chemistry)
Zdroj:	Dalton Transactions. 45:15298-15302
ISSN:	1477-9234 1477-9226
Popis:	Reactions of Sn–S clusters with [IrCl(cod)]2 afforded an Ir–Sn–S cluster with unprecedented topology, {[Ir3(cod)3(μ3-S)2](μ3-S)SnCl}2, in which two [Ir3S2] units and a central [Sn2S2] unit are connected via Ir–S and Ir–Sn bonds. Each of the crystallographically independent Ir atoms exhibits a specific chemical environment. Quantum chemical studies shed light on the electronic structure of the multinary cluster and the Ir–Sn bonds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ce44d92f57fa3ef302024bce8600e116 https://doi.org/10.1039/c6dt02910h Zobrazit plný text záznamu