A Comparison Study of Physicochemical Properties and Stabilities of H-Shaped Molecule and the Corresponding Polymer
| Autor: | Zongyan Zuo, Meng-Na Yu, Feng Quanyou, Bin Li, Bin Liu, Ying Wei, Ruidong Xia, Linghai Xie, Songlin Xie, Wei Huang |
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| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
010407 polymers Amplified spontaneous emission Materials science Polymers and Plastics General Chemical Engineering Chemical structure Organic Chemistry Polymer Fluorene 01 natural sciences Small molecule 0104 chemical sciences chemistry.chemical_compound Monomer chemistry Chemical engineering Molar mass distribution Molecule |
| Zdroj: | Chinese Journal of Polymer Science. 37:11-17 |
| ISSN: | 1439-6203 0256-7679 |
| DOI: | 10.1007/s10118-018-2152-5 |
| Popis: | Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and solution processing, were designed and synthesized. Optoelectronic properties and various kinds of stability features, including the thermostabilities, spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general, the corresponding polymer PH exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer H-1 probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly, monomer H-1 displayed a comparable ASE threshold value with its polymer PH, suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers. |
| Databáze: | OpenAIRE |
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