Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes

Autor:	Anthony F. Hill, Never Tshabang, Mark R. St J. Foreman, Chenxi Ma, Andrew J. P. White
Rok vydání:	2019
Předmět:	Inorganic Chemistry Substitution reaction chemistry.chemical_classification Double bond 010405 organic chemistry Chemistry Ligand 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences 3. Good health
Zdroj:	Dalton Transactions. 48:209-219
ISSN:	1477-9234 1477-9226
DOI:	10.1039/c8dt04278k
Popis:	Ruthenaboratranes of the form [Ru(CO)L{κ4-B(mt)3}] (mt = N-methimazolyl) arise via substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of [RuCl(R)(CO)Ln] (R = Ph, CHCHPh; n = 2, L = PCy3; n = 3, L = P(OMe)3, PMe2Ph) with Na[HB(mt)3].
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ce356421d32a066d33af5f7961b53ac5 https://doi.org/10.1039/c8dt04278k Zobrazit plný text záznamu