Synthesis, electrochemistry and spectroelectrochemistry of hydrazido(2-) bridged bimetallic molybdenum species, and the X-ray crystal structure of [Mo{HB(3,5-Me2pz)3}(NO)Cl]2(μ-NHNH) in solid solution

Autor:	Roman A. Kresinski, Jon A. McCleverty, Christopher J. Jones, Brian D. Neaves, Sean L.W. McWhinnie, Lesley J. Yellowlees, Stephen M. Charsley
Rok vydání:	2002
Předmět:	Component (thermodynamics) X-ray chemistry.chemical_element Crystal structure Electrochemistry Inorganic Chemistry Solvent Crystallography chemistry Molybdenum Materials Chemistry Physical and Theoretical Chemistry Bimetallic strip Solid solution
Zdroj:	Polyhedron. 21:849-857
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(02)00841-0
Popis:	The species [Mo{HB(3,5-Me2pz)3}(NO)Cl]2(μ-NHNH) (1) (3,5-Me2pz=3,5-dimethylpyrazol-1-yl) and [Mo{HB(3,5-Me2pz)3}(NO)I]2(μ-NHNH) have been synthesised. Electrochemical reduction of 1 results in a species with a near-infrared spectral band which shows no solvent dependence. Reoxidation results in the formation of another species which undergoes reversible reduction resulting in the development of another near-infrared spectral band which also is insensitive to solvent. These observations suggest that, in both cases, the mixed-valence species are class III. Additionally, 1 has been characterised structurally as a component of a solid solution also containing its chlorinated analogues; this determination shows that all components of the solution contain a near-planar MoNHNHMo array and that Cl replacement is isomorphous.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ce23856614ba52fc87be5c5fdbd26327 https://doi.org/10.1016/s0277-5387(02)00841-0 Zobrazit plný text záznamu Full Text from ScienceDirect