The preparation of some group VI fluorometal carbonyl derivatives

Autor:	J. K. Ruff, W.M. Douglas
Rok vydání:	1974
Předmět:	Chemistry Ligand Organic Chemistry Inorganic chemistry Infrared spectroscopy Metal carbonyl Biochemistry Medicinal chemistry Ion Inorganic Chemistry chemistry.chemical_compound Group (periodic table) Materials Chemistry Carbonyl derivatives Physical and Theoretical Chemistry Fluoride
Zdroj:	Journal of Organometallic Chemistry. 65:65-69
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)83887-5
Popis:	It has been found that fluoride ion can behave as a ligand towards the Group VI metal carbonyls. Thus the anions Cr(CO) 5 F − and W(CO) 5 F − were isolated and characterized. These products could be prepared by reaction of [(C 6 H 5 ) 3 P] 2 NF with the hexacarbonyls or by reaction of AgF with the dianions M 2 (CO) 10 2− (M = Cr or W). Their infrared spectra are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cdd642463367f704f5fd48c20522704a https://doi.org/10.1016/s0022-328x(00)83887-5 Zobrazit plný text záznamu