Behaviour of [RuClCp(mPTA)2](OSO2CF3)2 in water vs. the pH: Synthesis and characterisation of [RuCpX(mPTA)2](OSO2CF3)n, X=(H2O-κO, DMSO-κS, n=3; OH−-κO, n=2) (mPTA=N-methyl-1,3,5-triaza-7-phosphaadamantane)

Autor:	Pedro Gili, Manuel Serrano-Ruiz, Beatriz González, Pablo Lorenzo-Luis, Antonio Romerosa
Rok vydání:	2009
Předmět:	Inorganic Chemistry Stereochemistry Chemistry Organic Chemistry Materials Chemistry Crystal structure Nuclear magnetic resonance spectroscopy Physical and Theoretical Chemistry Thermal analysis Biochemistry Medicinal chemistry
Zdroj:	Journal of Organometallic Chemistry. 694:2029-2036
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2009.01.050
Popis:	The behaviour of [RuClCp(mPTA) 2 ](OSO 2 CF 3 ) 2 ( 1 ) in water solution vs . the pH was studied. Complex 1 is stable in neutral and acidic water solution while in basic water solution another complex, [RuCp(OH-κO)(mPTA) 2 ](OSO 2 CF 3 ) 2 ·(C 4 H 10 O) ( 2 ), is obtained. Complexes [RuCp(mPTA) 2 (L)]·X n (L = H 2 O-κ O , X = − OSO 2 CF 3, n = 3 ( 3 ); L = Cl, X = BF 4 - , n = 2 ( 4 ); L = DMSO-κ S , X = − OSO 2 CF 3 , n = 3 ( 5 )) were also obtained. All presented complexes were characterised by IR and multinuclear ( 1 H, 13 C{ 1 H}, 19 F{ 1 H}and 31 P{ 1 H}) NMR spectroscopy. Improved synthesis for 1 , the thermal analysis of complexes 1 – 3 and the crystal structure of the complexes 1 and 5 are also presented.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cdd10b8221ee9336bcb6bdfd93a51949 https://doi.org/10.1016/j.jorganchem.2009.01.050 Zobrazit plný text záznamu Full Text from ScienceDirect