Effect of Shear Stress on Viscosity and Crystallization Behavior of CaO-SiO2-Al2O3 Based Mold Fluxes

Autor: Guang Hua Wen, Jun Li Guo, Shao Peng Gu, Ping Tang
Rok vydání: 2020
Předmět:
Zdroj: Key Engineering Materials. 847:87-92
ISSN: 1662-9795
DOI: 10.4028/www.scientific.net/kem.847.87
Popis: The effect of shear stress on the viscosity and crystallization behavior of CaO-SiO2-Al2O3 based mold fluxes were investigated, and the structure evolution of molten slag under shear stress were characterized by magic-angle spinning nuclear magnetic resonance technology (MAS-NMR). The results showed that with an increase of shear stress, the shear-thinning behavior of molten slag was found, and the strongest shear-thinning behavior was formed with an addition of 15% Al2O3. Correspondingly, the decrement of Q3(1Al) and Q2(1Al) species in molten slag were the largest from MAS-NMR results. In addition, under agitation, the crystallization fraction of sample increased from 71% to 88%, and the average grain size was reduced 23%. However, the shear stress has no influence on the crystal phase.
Databáze: OpenAIRE