SYNTHESIS, STUDY, AND APPLICATIONS OF POLYMERIC N-HETEROCYCLIC CARBENES

Autor:	Christopher W. Bielawski, Alan H. Cowley, Adam B. Powell
Rok vydání:	2010
Předmět:	Inorganic Chemistry Chemistry Electrochromism chemistry.chemical_element Organic chemistry Iridium Combinatorial chemistry Diimine
Zdroj:	Comments on Inorganic Chemistry. 31:75-82
ISSN:	1548-9574 0260-3594
DOI:	10.1080/02603594.2010.517459
Popis:	A brief review of our work on orthogonally-positioned NHC metallopolymers is highlighted herein. Some pertinent literature is presented, followed by the synthetic strategy employed as well as comprehensive electrochemical analyses. Derivatization of a suitable diimine into a electropolymerizable gold (I) NHC complex resulted in the first orthogonally-positioned NHC metallopolymer. Extension of this methodology to prepare analogous group 11, iridium and sulfur-substituted metallopolymers generated thin films with electrochromic activity that could be tuned by proper selection of the metal center.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cdcc20a2e8c7950adeab93afa91f4c7a https://doi.org/10.1080/02603594.2010.517459 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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