Trifluoro methyl peroxynitrate (CF3OONO2): Temperature dependence of the UV absorption spectrum and atmospheric implications

Autor: Gustavo A. Argüello, Malisa S. Chiappero, Fabio E. Malanca, Timothy J. Wallington
Rok vydání: 2005
Předmět:
Zdroj: Atmospheric Environment. 39:5051-5057
ISSN: 1352-2310
Popis: The ultraviolet absorption spectrum of gas phase CF3OONO2 has been measured over the wavelength range 200–340 nm at 233–300 K. Absorption cross-sections at wavelengths of 290–340 nm were found to increase significantly with increasing temperature. The UV spectra of CF3C(O)Cl and CF3C(O)F were measured and were consistent with previous work [Rattigan et al., 1993. Temperature-dependent absorption cross-sections of CF3COCl, CF3COF, CH3COF, CCl3CHO and CF3COOH. Journal of Photochemistry and Photobiology A: Chemistry 73, 1–9]. Implications for the atmospheric chemistry of CF3OONO2 are discussed.
Databáze: OpenAIRE