Change in the mechanism of conductivity in ZrO2-based crystals depending on the content of stabilizing Y2O3 additive
| Autor: | Vladimir T. Bublik, Elena E. Lomonova, Sergey Bredikhin, S. V. Seryakov, M. A. Borik, Alexey V. Kulebyakin, Valentina A. Myzina, N. Yu. Tabachkova, Filipp Milovich, V. V. Osiko, I. E. Kuritsyna |
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| Rok vydání: | 2017 |
| Předmět: |
Materials science
Physics and Astronomy (miscellaneous) 010308 nuclear & particles physics Analytical chemistry 02 engineering and technology Conductivity 021001 nanoscience & nanotechnology 01 natural sciences Oxygen atom Phase composition Phase (matter) 0103 physical sciences Content (measure theory) Fast ion conductor Ionic conductivity 0210 nano-technology |
| Zdroj: | Technical Physics Letters. 43:289-292 |
| ISSN: | 1090-6533 1063-7850 |
| DOI: | 10.1134/s1063785017030166 |
| Popis: | The interrelationship between the structure, phase composition, and transport characteristics of solid electrolytes based on ZrO2 has been studied as dependent on the content of stabilizing Y2O3 additive. It is established that twin boundaries do not lead to the appearance of additional mechanism of ionic conductivity acceleration in ZrO2–Y2O3 crystals. The maximum conductivity has been observed in ZrO2–(8–10) mol % Y2O3 crystals containing a t” phase, in which oxygen atoms are displaced from high-symmetry positions characteristic of the cubic phase. |
| Databáze: | OpenAIRE |
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