Long-lived 1-adamantaneimminyl free radical as studied by ESR in 1-cyanoadamantane

Autor:	J. Roncin, Henri Szwarc, J.P. Michaut, J.J. Pinvidic
Rok vydání:	1985
Předmět:	Molecular dynamics Radical ion Chemistry Radical Analytical chemistry General Physics and Astronomy Physical and Theoretical Chemistry Spin label Spectroscopy Photochemistry 1-cyanoadamantane
Zdroj:	Chemical Physics Letters. 120:555-558
ISSN:	0009-2614
DOI:	10.1016/0009-2614(85)80554-6
Popis:	The products of γ-irradiation of 1-cyanoadamantane were studied as a function of temperature by ESR spectroscopy. 1-adamantyl, 1-cyanoadamantyl and 1-adamantaneimminyl free radicals are formed in proportions depending on temperature. The low-temperature major product, 1-cyanoadamantyl transforms upon heating into the imminyl free radical which can be used as a spin label for studying molecular dynamics in glassy crystalline 1-cyanoadamantane.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cdb146b4b262adda8ce2fdadd0775438 https://doi.org/10.1016/0009-2614(85)80554-6 Zobrazit plný text záznamu