Alkylation of carbonyl compounds with dialkylzirconocene complexes promoted by potassium t-butoxide

Autor:	Robert W. Towne, Daniel A. Straus, Diana L. Baker, Ann L. Larson
Rok vydání:	1991
Předmět:	chemistry.chemical_classification Ketone Chemistry Potassium Organic Chemistry chemistry.chemical_element Alkylation Biochemistry Aldehyde Ion Metal chemistry.chemical_compound visual_art Drug Discovery Polymer chemistry Alkoxide visual_art.visual_art_medium Organic chemistry Metallocene
Zdroj:	Tetrahedron Letters. 32:5893-5894
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)79419-6
Popis:	Potassium t -butoxide promotes alkylation of non-enolizable ketones and aldehydes by zirconocene dialkyls. The reaction proceeds with loss of cyclopentadienide ion from the metal center.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cda7cfca1bf32487202020f90cef0d9a https://doi.org/10.1016/s0040-4039(00)79419-6 Zobrazit plný text záznamu