Silica functionalized Cu(II) catalysed selective oxidation of benzyl alcohols using TEMPO and molecular oxygen as an oxidant

Autor:	Pankaj Sharma, Manjulla Gupta, Rajive Gupta, Monika Gupta
Rok vydání:	2015
Předmět:	Primary (chemistry) chemistry X-ray photoelectron spectroscopy Polymer chemistry Inorganic chemistry chemistry.chemical_element General Chemistry Molecular oxygen Fourier transform infrared spectroscopy Copper Oxygen humanities Catalysis
Zdroj:	Journal of Chemical Sciences. 127:1485-1489
ISSN:	0973-7103 0974-3626
DOI:	10.1007/s12039-015-0902-2
Popis:	A general scheme for the oxidation of benzyl alcohols catalyzed by silica functionalized copper (II) has been designed. TEMPO, a free radical, assists this oxidation that was initiated by molecular oxygen which converts it to a primary oxidant. This catalytic combination i.e. SiO2-Cu(II) in presence of TEMPO and oxygen provides excellent results in terms of yields and reaction time. SiO2-Cu(II) was very well characterized by different spectroscopic techniques such as FTIR, XRD, TGA, XPS, EDAX, SEM, TEM and AAS and is recyclable upto five times which makes it economically beneficial.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cd947ed063fd49dfb33384729fa4dcdb https://doi.org/10.1007/s12039-015-0902-2 Zobrazit plný text záznamu Plný text ve formátu PDF