Synthesis of nitrogen- or oxygen- containing ring systems by palladium-catalyzed intramolecular olefin allylations

Autor:	J. Hueso-Rodriguez, Wolfgang Oppolzer, Jean-Marc Gaudin, T. M. Raynham, C. Robyr, M. Bedoya-Zurita
Rok vydání:	1988
Předmět:	Olefin fiber Intramolecular reaction Organic Chemistry chemistry.chemical_element Ether Biochemistry Medicinal chemistry Crotyl chemistry.chemical_compound chemistry Intramolecular force Drug Discovery Organic chemistry Ene reaction Tetrahydrofuran Palladium
Zdroj:	Tetrahedron Letters. 29:4709-4712
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)80587-0
Popis:	Pd(PPh 3 ) 4 -catalyzed cyclizations of N -allyl(crotyl, or 3-butenyl), N -butenyloxy derivatives and of an allyl(2-butenyloxy) ether give pyrrolidines, piperidines and a tetrahydrofuran in good yields. Hexahydroindoles and octahydroquinolines are thus obtained from the corresponding N -(2- or 3-butenyl), N -(4-acetoxy-2-cyclohexenyl) amides with excellent stereocontrol.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cd92ee596b3c2a76709f96546baa979e https://doi.org/10.1016/s0040-4039(00)80587-0 Zobrazit plný text záznamu