Cobalt Fluorocarbene Complexes
| Autor: | Serge I. Gorelsky, Ilia Korobkov, R. Tom Baker, Graham M. Lee, Daniel J. Harrison |
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| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Organometallics. 32:12-15 |
| ISSN: | 1520-6041 0276-7333 |
| Popis: | Unusual nucleophilic cobalt fluorocarbene complexes ([CoI]═CFR; R = F, CF3) are described. Only a handful of fluorocarbenes of first-row transition metals have been reported, and these have exhibited electrophilic reactivity at the metal–carbene bonds. The title compounds are the first persistent/isolable cobalt fluorocarbenes and also rare examples of metal fluorocarbenes with relatively nucleophilic M═C bonds (vs other metal fluorocarbene complexes), demonstrated by their reactions with H+ and Me+ and their unusual stability toward water. X-ray crystal structures reveal the shortest terminal cobalt–carbene bonds reported to date, and DFT studies provide details into the nature of these bonds. |
| Databáze: | OpenAIRE |
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