ChemInform Abstract: Catalytic Asymmetric Thiofunctionalization of Unactivated Alkenes

Autor:	Scott E. Denmark, David J. P. Kornfilt, Thomas Vogler
Rok vydání:	2012
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Double bond Nucleophile Electrophile Intermolecular force Organic chemistry chemistry.chemical_element General Medicine Phosphoramide Sulfur Catalysis
Zdroj:	ChemInform. 43
ISSN:	0931-7597
DOI:	10.1002/chin.201212031
Popis:	Catalytic asymmetric sulfenylation of double bonds has been achieved using a BINAM-based phosphoramide catalyst and an electrophilic sulfur source. Simple alkenes as well as styrenes afforded sulfenylated tetrahydrofurans and tetrahydropyrans by closure with pendant hydroxyl or carboxyl groups. Intermolecular thiofunctionalizations were also achieved with simple alcohols or carboxylic acids as the nucleophiles.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cd739e18c697551ed0697a7b3dbc1287 https://doi.org/10.1002/chin.201212031 Zobrazit plný text záznamu Plný text