Study on unsaturated structures of polyhexene, poly(4-methylpentene) and poly(3-methylpentene) prepared with metallocene catalysts

Autor:	Junji Saito, Hideyuki Kaneko, Norio Kashiwa, Shingo Matsuo, Yoshihisa Toda, Nobuo Kawahara, Tomoaki Matsugi
Rok vydání:	2007
Předmět:	chemistry.chemical_classification Polymers and Plastics Organic Chemistry Methylaluminoxane Polymer Catalysis chemistry.chemical_compound chemistry Hexene Polymer chemistry Materials Chemistry Proton NMR Organic chemistry Metallocene
Zdroj:	Polymer. 48:425-428
ISSN:	0032-3861
DOI:	10.1016/j.polymer.2006.11.001
Popis:	Hex-1-ene (hexene), 4-methylpent-1-ene (4-MP-1) and 3-methylpent-1-ene (3-MP-1), homopolymerizations were conducted by using metallocenes, En(Ind) 2 ZrCl 2 and i Pr(Cp)(Flu)ZrCl 2 , with methylaluminoxane. 1 H NMR analyses of the resulting polymers were carried out to identify the unsaturated structures of these polymers. In polyhexene and poly(4-MP-1), the detected main unsaturated structure was di-substituted vinylene. On the other hand, in poly(3-MP-1), vinylidene and tri-substituted vinylene structures were mainly observed for the first time.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cd55a03b830b29c201d08c77376641bf https://doi.org/10.1016/j.polymer.2006.11.001 Zobrazit plný text záznamu Full Text from ScienceDirect