Synthesis, structures and properties of hydrolytic Al(III) aggregates and Fe(III) analogues formed with iminodiacetate-based chelating ligands

Autor:	Christopher E. Anson, Geoffrey R. Moore, Annie K. Powell, Peter Jordan, Richard K. Henderson, Wolfgang Schmitt
Rok vydání:	2002
Předmět:	Inorganic Chemistry Hydrolysis Aqueous solution Chelating ligands Chemistry Metal ions in aqueous solution Inorganic chemistry Polymer chemistry Materials Chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Ion
Zdroj:	Coordination Chemistry Reviews. 228:115-126
ISSN:	0010-8545
Popis:	Both Al(III) and Fe(III) display a rich hydrolytic chemistry which can lead to the formation of a variety of aggregated oxo and hydroxo-bridged aggregates. The formation, structures and properties of these species are important in defining the availability and reactivity of these species in aqueous environments such as are found in biological systems and the environment. Although there are many similarities in the behaviour of the Al3+ and Fe3+ ions there are also some important differences between these two metal ions which can lead to a divergence in their chemistries. These considerations are discussed and illustrated with reference to 16 Al(III) and Fe(III) compounds, which have been crystallographically characterised, and which form in aqueous environments in the presence of chelating ligands containing the iminodiacetate functionality.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cd532b9012dabfa010998a6cd6ca6d02 https://doi.org/10.1016/s0010-8545(02)00110-8 Zobrazit plný text záznamu Full Text from ScienceDirect