Nitration of fluoroethylenes by nitrating mixture (HNO3+H2O4+SO3)

Autor: Valery K. Brel, I. V. Martynov, A. V. Yarkov, V. I. Uvarov, V. I. Anufriev
Rok vydání: 1989
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 38:2500-2503
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00962433
Popis: The nitration of fluoroethylenes with sulfuric-nitric mixtures and added sulfuric anhydride was studied. It was shown that acid fluorides of halogenonitroacetic acids are formed in the nitration of fluoroethylenes containing the fluorochloromethylene fragment, whereas nitroethylfluorosulfates are the main reaction product in the nitration of ethylenes having the difluoromethylene grouping. The structure of the compounds obtained was shown by the data of19F and1H NMR and IR spectroscopy.
Databáze: OpenAIRE