Crystal Structure, Thermal Behavior, and Non-Isothermal Kinetics of a New Dinuclear Ni(II) Complex

Autor:	Zhongjun Li, Xiao-Na Fan, Hong-Yun Zhang, Xiao-Qing Shen
Rok vydání:	2010
Předmět:	Inorganic Chemistry Metal Crystallography Chemistry visual_art Kinetics Thermal Thermal decomposition visual_art.visual_art_medium Crystal structure Physical and Theoretical Chemistry Thermal analysis Isothermal kinetics
Zdroj:	Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 40:410-415
ISSN:	1553-3182 1553-3174
DOI:	10.1080/15533174.2010.492553
Popis:	Single crystals of a new complex, [Ni 2 (μ-H 2 O) (CH 3 OH) 2 (L) 2 ]H 2 OCH 3 OH (1), of metal Ni(II) atoms were obtained by using a new ligand, 2,6-di(N,N′-5-ethyl-1,3,4-thiadiazole-2-formamide)-pyridine (H2L). Complex 1 is a dinuclear one containing a triangle frame formed by two metal Ni(II) with a bridging H 2 O, in which H 2 L coordinates two metal centers as a tetra-dentate ligand. Thermal analysis shows that the decomposition of complex 1 can be devided into two transitions, and non-isothermal kinetics studies show that the thermal decomposition mode of complex 1 is a double-step following reaction
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cd3b5d45c428ab0ea4f38d211776a7ca https://doi.org/10.1080/15533174.2010.492553 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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