Reactions of a cationic bridging methylidyne complex with activated alkenes

Autor:	Mark A. Gohdes, Charles P. Casey, Mark W. Meszaros
Rok vydání:	1986
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Stereochemistry Organic Chemistry Cationic polymerization Carbyne Physical and Theoretical Chemistry Medicinal chemistry Chemical reaction
Zdroj:	Organometallics. 5:196-199
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om00133a003
Popis:	Etude de la reaction de [(C 5 H 5 ) 2 (CO) 2 Fe 2 (μ-CO)(μ-CH)] + PF 6 − (1) avec l'allyltriphenyletain et l'allyltrimethylsilane. Elle donne (C 5 H 5 ) 2 (CO) 2 Fe 2 (μ-CO)(μ-CHCH 2 CH=CH 2 ). On etudie aussi les reactions de (1) avec (dimethylphenylsilyl)-2propene et l'acetate de vinyle
Databáze:	OpenAIRE
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