Reactivity of co-micellar systems based on dimeric functionalized tetraalkylammonium surfactant in phosphoryl and sulfonyl group transfer processes
| Autor: | I. A. Belousova, I. V. Kapitanov, A. A. Serdyuk, T. M. Prokop’eva, M. K. Turovskaya, N. G. Razumova, M. L. Kostrikin, A. E. Shumeiko |
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| Rok vydání: | 2017 |
| Předmět: |
Sulfonyl
chemistry.chemical_classification 010405 organic chemistry Chemistry Organic Chemistry Kinetics Cationic polymerization 010402 general chemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Pulmonary surfactant Intramolecular force Polymer chemistry Organic chemistry Molecule Reactivity (chemistry) Acyl group |
| Zdroj: | Russian Journal of Organic Chemistry. 53:510-513 |
| ISSN: | 1608-3393 1070-4280 |
| DOI: | 10.1134/s1070428017040029 |
| Popis: | The reactivity of co-micellar systems based on dimeric functionalized tetraalkylammonium surfactant in phosphoryl and sulfonyl group transfer processes is lower than the reactivity of systems based on analogous imidazolium surfactant. The observed difference in the kinetics of acyl group transfer promoted by dimeric surfactants differing by the nature of the cationic center is likely to be general, and it results from both different nucleophilicities of their oximate fragments and different modes of solubilization of hydrophobic substrates. The most probable reasons for the latter are differences in intramolecular Coulomb interactions and packing of surfactant molecules in co-micelles. |
| Databáze: | OpenAIRE |
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