A mass spectroscopic study of compounds from the cyclopropane series. 3. Behavior of alkoxy- and aryloxy-gem-dichlorocyclopropanes under electron impact

Autor:	T. K. Tetushkina, O. S. Chizhov, V. I. Kadentsev, S. M. Shostakovskii, A. A. Petinskii
Rok vydání:	1978
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Principal direction Chemistry Alkoxy group General Chemistry Photochemistry Decomposition Medicinal chemistry Alkyl Electron ionization Ion Cyclopropane
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:319-325
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00923868
Popis:	1. The principal direction of alkoxy-gem-dichlorocyclopropane M+ ion breakdown is that leading to the formation of gem-dichlorocyclopropyl ions, and the alkyl ions resulting from their decomposition, together with rearranged fragments with m/e 90, 91. 2. Under electron impact, the aryloxy-gem-dichlorocyclopropanes give aromatic gem-dichlorocyclopropyl fragments, together with the ions, ArO+, ArO+, [M-Cl]+, [M-Cl, -CO]+, and [M-Cl, -HCl, -CO]+ ions. 3. Conditions favoring and inhibiting these various processes have been given.
Databáze:	OpenAIRE
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