Chiral Bis(oxazolinyl)phenyl Rhodium and Palladium Complexes

Autor:	Nobuyuki Makihara, Katsuyuki Aoki, Yukihiro Motoyama, Hisao Nishiyama, Yoshiharu Mikami
Rok vydání:	1997
Předmět:	Transmetalation chemistry chemistry.chemical_element Organic chemistry General Chemistry Crystal structure Medicinal chemistry Rhodium Palladium
Zdroj:	Chemistry Letters. 26:951-952
ISSN:	1348-0715 0366-7022
Popis:	The transmetalation of Phebox-ip-SnMe3 [Phebox = 2,6-bis(oxazolinyl)phenyl] 1c with RhCl3(H2O)3 and PdCl2(PhCN)2 gave (Phebox-ip)RhCl2(H2O) 2a and (Phebox-ip)PdCl 3 under mild conditions in 45% and 96% yields, respectively. The crystal structures of (Phebox-ip)RhCl2(t-BuNC) 2b, which was obtained by the reaction of 2a with t-BuNC, and 3 have been determined by X-ray diffraction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ccbf14724a1842d86c808d7506f202a6 https://doi.org/10.1246/cl.1997.951 Zobrazit plný text záznamu