Unexpected inversion of configuration at a quaternary centre during the acetolysis ofD -homo-5α-androstan-17aβ-yl tosylate
| Autor: | David N. Kirk, C. M. Peach, Ismail Khattak, M. A. Wilson |
|---|---|
| Rok vydání: | 1973 |
| Předmět: | |
| Zdroj: | J. Chem. Soc., Chem. Commun.. :341-341 |
| ISSN: | 0022-4936 |
| Popis: | Acetolysis of D-homo-5α-androstan-17aβ-yl tosylate (I) gave the 17aβ-yl acetate (II) accompanied by D-homo-5α,13α-androstan-17aα-yl acetate (III), resulting from inversion of configuration at the quaternary centre adjacent to the reaction site. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|