Stable and Active Mixed Zr–Ce Oxides for Catalyzing the Gas Phase Oxidation of HCl

Autor: Rüdiger Ellinghaus, Christian H. Kanzler, Stefan F. Rohrlack, Herbert Over, Bernd M. Smarsly, Peter J. Klar, Limei Chen, Sven Urban, Nikolay Tarabanko, K. Zalewska-Wierzbicka
Rok vydání: 2013
Předmět:
Zdroj: Catalysis Letters. 143:1362-1367
ISSN: 1572-879X
1011-372X
DOI: 10.1007/s10562-013-1091-6
Popis: Electrospun mixed Zr1−x Ce x O2 nanofibers were used to assess both the activity in the Deacon process and the morphological stability of these model catalysts under harsh HCl oxidation conditions. CeO2 nanofibers are morphologically unstable, while Zr doping stabilizes CeO2 nanofibers. Already 30 % of Ce results in high activity of Zr1−x Ce x O2 nanofibers.
Databáze: OpenAIRE