A heterogenized vanadium oxo-aroylhydrazone catalyst for efficient and selective oxidation of hydrocarbons with hydrogen peroxide

Autor:	Hassan Hosseini Monfared, Massomeh Ghorbanloo, Alireza Aghaei, Vahideh Abbasi, Adineh Rezaei
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Schiff base Silica gel Metals and Alloys Vanadium chemistry.chemical_element Catalysis Inorganic Chemistry chemistry.chemical_compound Hydrocarbon chemistry Salicylaldehyde Polymer chemistry Materials Chemistry Organic chemistry Hydrogen peroxide Benzene
Zdroj:	Transition Metal Chemistry. 37:85-92
ISSN:	1572-901X 0340-4285
DOI:	10.1007/s11243-011-9561-4
Popis:	A hydrazone Schiff base ligand derived from salicylaldehyde and benzhydrazide has been synthesized and reacted with vanadium(IV) leading to the corresponding vanadium(V) complex. The complex has been anchored on the surface of functionalized silica gel by N,O-coordination to the covalently Si–O bound modified salicylaldiminato ligand. The supported complex has been evaluated as a catalyst for hydrocarbon oxidation with hydrogen peroxide in acetonitrile. The heterogeneous system proved to be an efficient catalyst and was able to activate hydrogen peroxide toward the oxidation of alkenes, alkanes, benzene, and alkylaromatic compounds with more than 2,500 h−1 activity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cc94e45ca40487c803f185be980717c9 https://doi.org/10.1007/s11243-011-9561-4 Zobrazit plný text záznamu Full text from SpringerLink