Neutral Ammonium Citrate Extraction of Biosolids Phosphorus

Autor: George A. O'Connor, R. C. Brandt, H. A. Elliot, J. M. Potter, Jihoon Kang
Rok vydání: 2005
Předmět:
Zdroj: Communications in Soil Science and Plant Analysis. 36:2447-2459
ISSN: 1532-2416
0010-3624
Popis: Matching biosolids application rates to crop phosphorus (P) needs requires quantifying the P fertilizer replacement value of biosolids. Neutral ammonium citrate (NAC) extraction of P, used for assessing available P in mineral fertilizers, was evaluated for 35 different biosolids. Biosolids NAC‐P was not statistically different (p=0.05) from total P using strong acid digestion (EPA 3051‐P). High P recovery by NAC was attributed to dissolution of P‐containing iron (Fe)/aluminum (Al) oxides under the aggressive extracting conditions (0.88 M citrate at 65°C). Citrate effectively dissolves P‐binding Fe/Al hydrous oxides, the very components that reduce phytoavailability when biosolids are land applied. Greenhouse studies with pasture grass (Paspalum notatum Flugge) grown in P‐deficient soils amended with biosolids revealed P phytoavailability was not correlated (r2=0.10) with biosolids NAC‐P. Phytoavailability was inversely correlated (r2=0.66) with biosolids total Al+Fe content. The NAC extraction, d...
Databáze: OpenAIRE