Carborane-containing 3,6-di-tert-butyl-o-semiquinolate complexes of tin

Autor:	M. V. Petriashvili, Z. K. Kasymbekova, M. I. Kabachnik, N. N. Bubnov, N. N. Godovnikov, Vladimir I. Bregadze, S. P. Solodovnikov, V. Ts. Kampel, A. I. Prokof'ev
Rok vydání:	1983
Předmět:	Tert butyl Chemistry Radical Chlorine atom chemistry.chemical_element General Chemistry Photochemistry chemistry.chemical_compound Metal halides Polymer chemistry Atom Acetone Carborane Tin
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 32:282-289
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00957933
Popis:	1. Carborane-containing 3,6-di-tert-butyl-o-semiquinolate complexes of tin, depending on the nature of the substituents, are either oxygen-centered radical complexes or chelatestructure complexes. 2. For the radicals with a hexacoordinated tin atom in polar solvents (THF, acetone), permutational shifts of the chlorine atom have been studied. 3. By the action of metal halides (CsCl, LiF) on oxygen-centered phenoxyl carborane-containing radical complexes of tin, anion-radical complexes are formed.
Databáze:	OpenAIRE
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