Facile control of preferred geometry of pentadienyl-potassium by changing the medium: 'U'-shaped in solution and 'W'-shaped in the solid state

Autor:	Hajime Yasuda, Michihide Yamauchi, Akira Nakamura
Rok vydání:	1980
Předmět:	Inorganic Chemistry Crystallography Chemistry Potassium Organic Chemistry Materials Chemistry Solid-state Proton NMR Chemical trapping chemistry.chemical_element Physical and Theoretical Chemistry Biochemistry
Zdroj:	Journal of Organometallic Chemistry. 202:C1-C5
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)81389-3
Popis:	The structure of pentadienylpotassium in THF was determined to be the U-shaped by chemical trapping with chlorotrimethylsilane and from the 1H NMR spectrum. The results of trimethylsilylation of pentadienylpotassium in the solid state indicate that it assumes the W-shaped structure in the crystalline state.
Databáze:	OpenAIRE
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