Novel rearrangement of prop-2-ynyl N-Oxides to hydroxylamine O-allenyl ethers: mechanistic studies

Autor:	Nnochiri N. Ekwuribe, J. Cymerman Craig, Larry D. Gruenke
Rok vydání:	1979
Předmět:	chemistry.chemical_compound Product analysis Hydroxylamine chemistry Deuterium Computational chemistry Organic Chemistry Drug Discovery Organic chemistry Biochemistry
Zdroj:	Tetrahedron Letters. 20:4025-4028
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(01)86494-7
Popis:	The novel thermolytic rearrangement of prop-2-ynyl N-Oxides to hydroxylamine O-allenyl ethers has been examined by deuterium labeling. Product analysis by gc-eims and by cims has shown the reaction to proceed by a concerted cyclic transition state.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cc4f6b0714b1164e93b7acefa2d0ed27 https://doi.org/10.1016/s0040-4039(01)86494-7 Zobrazit plný text záznamu