Photoresponsive molecular tweezer: Control-release of anions and fluorescence switch
| Autor: | Shuqiang Mao, Leng Juhua, Puyang Dong, Tian-Wei Cui, Wannian Liu, Xin-Qi Hao, Mao-Ping Song, Guoxing Liu |
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| Rok vydání: | 2021 |
| Předmět: |
Photoisomerization
Chemistry Process Chemistry and Technology General Chemical Engineering Supramolecular chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Fluorescence 0104 chemical sciences Ion Cell membrane medicine.anatomical_structure Drug delivery medicine Surface modification 0210 nano-technology Ion transporter |
| Zdroj: | Dyes and Pigments. 184:108838 |
| ISSN: | 0143-7208 |
| Popis: | Photoresponsive control-release supramolecular systems have aroused considerable interest for the application in drug delivery, ion transport and so on. Here, we fabricated a stiff-stilbenes-based bis-urea that resembles a molecular tweezer, exhibiting reversible photoisomerization behaviors between (Z)-form and (E)-form. Significantly, photo-controlled selective recognition and release of CH3CO2− and H2PO4− were achieved by the molecular tweezer upon irradiation with distinct light. Furthermore, the stiff-stilbenes-based bis-urea also hold a functionalization as a novel photoinduced fluorescence switch. These finds have enormous potential for the application in optically controlled drug delivery, the regulation of anion transport across the cell membrane and advanced optical materials. |
| Databáze: | OpenAIRE |
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