Assessing chiral self-recognition using chiral stationary phases

Autor: Huei-Shian Lin, James R. Carey, William H. Pirkle, Wonjae Lee, Phillip I. Volkers, Bin-Syuan Huang, William A. Boulanger, David A. Engebretson, Seth E. Snyder
Rok vydání: 2011
Předmět:
Zdroj: Tetrahedron. 67:7143-7147
ISSN: 0040-4020
DOI: 10.1016/j.tet.2011.06.103
Popis: Chiral stationary phases were synthesized and their ability to separate racemic precursors from which they were derived was assessed. Taken in conjunction with homochiral recognition previously observed in the solid state, the results of this study reveal that a geometrically controlling π–π interaction has a profound influence on molecular recognition.
Databáze: OpenAIRE