| Autor: |
Raffaello Lazzaroni, Sergio Bertozzi, Paolo Pertici, Giovanni Fabrizi |
| Rok vydání: |
1990 |
| Předmět: |
|
| Zdroj: |
Journal of Molecular Catalysis. 58:75-85 |
| ISSN: |
0304-5102 |
| Popis: |
The influence of the reaction parameters (temperature, gas pressure) on the chemo- and regioselectivity of 1-hexene hydroformylation in the presence of Rh4(CO)12 as catalytic precursor has been investigated at partial and complete conversion. Both chemo- and regioselectivity are independent of the substrate conversion until 1-hexene is present in the reaction mixture. Chemoselectivity to aldehydes is complete at room temperature, while at higher temperatures it decreases with decreasing pressure and increasing temperature as a consequence of 1-hexene isomerization to (E)- and (Z)-2-hexenes. Similar amounts of heptanal and 2-methylhexanal are obtained at room temperature. At higher temperature and partial substrate conversion, only 1-hexene is converted to aldehydes; the regioselectivity towards the linear isomer increases from 4% at room temperature to 48% at 120 °C and is not affected by the gas pressure. Differing behaviours of the linear and branched alkyl metal intermediates towards the β-hydride elimination under the reaction conditions account for the influence of the reaction parameters on the chemo- and regioselectivity in 1-alkene hydroformylation. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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