Vapor-liquid equilibrium data for fatty acids and fatty methyl esters at low pressures

Autor:	C. J. Marlies, J. A. Monick, H. D. Allen
Rok vydání:	1946
Předmět:	chemistry.chemical_classification Work (thermodynamics) chemistry.chemical_compound Chromatography chemistry General Chemical Engineering Organic Chemistry Vapor–liquid equilibrium Myristic acid Raoult's law Fatty acid Polymer Lauric acid
Zdroj:	Oil & Soap. 23:177-182
ISSN:	1558-9331 0003-021X
DOI:	10.1007/bf02545630
Popis:	The experimental vapor-liquid equilibrium data obtained with a mixture of methyl esters, and a mixture of a fatty acid and the corresponding methyl ester, were in agreement with calculated Raoult’s law data at a pressure of 4.0±0.2 mm. Hg. The system lauric acid-myristic acid was observed to be non-ideal or not obeying Raoult’s law at a pressure of 4.0±0.2 mm. Hg. An average rate of polymer formation of 0.23% per hour at 155–170° C. was determined for mixtures of lauric acid and myristic acid. The above work shows the feasibility of obtaining useful vapor-liquid equilibrium data for fatty materials at low pressures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cbfbf0ed4a52b419008790811ce206cc https://doi.org/10.1007/bf02545630 Zobrazit plný text záznamu Full text from SpringerLink