Fischer-Tropsch Catalysts Based on Zr-Fe Intermetallides Encapsulated in an Al2O3/Al Matrix

Autor:	S. V. Tsybulya, A. N. Salanov, E. I. Bogolepova, G. S. Litvak, S. F. Tikhov, Vladislav A. Sadykov, E. V. Slivinskii, V. P. Mordovin, Yu. N. Dyatlova, V. I. Kurkin, A. E. Kuz'min, V. B. Fenelonov
Rok vydání:	2005
Předmět:	Chemistry Mineralogy Fischer–Tropsch process General Chemistry Cermet Catalysis Computer Science Applications law.invention chemistry.chemical_compound Transition metal Chemical engineering law Modeling and Simulation Aluminium oxide Calcination Particle size Texture (crystalline)
Zdroj:	Kinetics and Catalysis. 46:743-751
ISSN:	1608-3210 0023-1584
Popis:	ZrFe and ZrFe2 intermetallides in an Al2O3/Al cermet matrix are reported as catalysts for the fixed-bed Fischer-Tropsch synthesis, and the effects of some preparation conditions on their texture, structural, mechanical, and catalytic properties are discussed. A nonmonotonic dependence of their catalytic activity on the size of interametallide particles is observed. The selectivity, activity, and mechanical strength of the composites depend on the calcination temperature and on the place of the hydriding step in the catalyst preparation procedure. In terms of volumetric efficiency, the catalysts prepared are comparable with bulk, unencapsulated intermetallides and are among the most efficient iron-containing catalysts known to date.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cbe11f7a43c3a00630e1a9bfa05b1323 https://doi.org/10.1007/s10975-005-0131-7 Zobrazit plný text záznamu Plný text ve formátu PDF