Ferrocene-based aminophosphine ligands in the Ru(II)-catalysed asymmetric hydrogenation of ketones: assessment of the relative importance of planar versus carbon-centred chirality

Autor:	Stanley M. Roberts, Weiping Chen, William Mbafor, John Whittall
Rok vydání:	2006
Předmět:	Stereochemistry Organic Chemistry Asymmetric hydrogenation chemistry.chemical_element Planar chirality Medicinal chemistry Catalysis Inorganic Chemistry chemistry.chemical_compound Planar Ferrocene chemistry Physical and Theoretical Chemistry Chirality (chemistry) Carbon
Zdroj:	Tetrahedron: Asymmetry. 17:1161-1164
ISSN:	0957-4166
DOI:	10.1016/j.tetasy.2006.04.033
Popis:	Several ferrocene-based aminophosphine ligands have been prepared and shown to be effective in the Ru(II)-catalysed asymmetric hydrogenation of ketones. The enantioselectivity is mainly determined by the carbon-centred chirality of the ligands but the planar chirality is also important such that ( R C , S Fc )- or ( S C , R Fc )- are the matched chiralities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cbca9e0c3352a158df1a02876fc4b7ef https://doi.org/10.1016/j.tetasy.2006.04.033 Zobrazit plný text záznamu Full Text from ScienceDirect