Coordination of Bimuth(III) to Cucurbit[8]uril. Preparation and X-ray Structure of [{Bi(NO3)(H2O)5}2(Q8)][Bi(NO3)3(H2O)4]2[Bi(NO3)5]2·Q8·19H2O

Autor:	T. V. Mitkina, Olga A. Gerasko, Maxim N. Sokolov, Rosa Llusar, A. V. Virovets, Vladimir P. Fedin
Rok vydání:	2003
Předmět:	Inorganic Chemistry Crystallography Denticity Cucurbituril Chemistry X-ray chemistry.chemical_element Crystal structure Bismuth
Zdroj:	Zeitschrift für anorganische und allgemeine Chemie. 629:2440-2442
ISSN:	1521-3749 0044-2313
Popis:	Bi(NO3)3 reacts with cucurbit[8]uril, (Q8), in 3M HNO3 to give the title complex whose structure includes three discrete Bi complexes: [{Bi(NO3)(H2O)5}2(Q8)]4+ (CN of Bi = 9, both NO3— and cucurbit[8]uril are bidentate), [Bi(NO3)5]2— (CN of Bi = 10, all NO3— are bidentate), and [Bi(NO3)3(H2O)4] (CN of Bi = 10, all NO3— are bidentate).
Databáze:	OpenAIRE
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