Activation of silanes by Grubbs’ carbene complex Cl2(PCy3)2RuCHPh: dehydrogenative condensation of alcohols and hydrosilylation of carbonyls

Autor:	Reagan L. Miller, Daesung Lee, Sarah V. Maifeld
Rok vydání:	2002
Předmět:	chemistry.chemical_compound Silanes chemistry Silylation Hydrosilylation Organic Chemistry Drug Discovery Condensation Organic chemistry Biochemistry Carbene Catalysis Silyl ether
Zdroj:	Tetrahedron Letters. 43:6363-6366
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(02)01385-0
Popis:	This manuscript describes two catalytic methods for silyl ether synthesis using Grubbs’ catalyst Cl 2 (PCy 3 ) 2 RuCHPh. Silyl ethers are obtained from the reaction of a variety of silanes with alcohols by dehydrogenative condensation and by the hydrosilylation of carbonyl compounds. Both reactions occur under neat conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cbb174c3023b19160eddf189746a757b https://doi.org/10.1016/s0040-4039(02)01385-0 Zobrazit plný text záznamu Full Text from ScienceDirect