Measurements and simulations of ignition delay times and laminar flame speeds of nonane isomers
| Autor: | Daisuke Shimokuri, Takuma Endo, Fumihiko Saito, Shenqyang Shy, Tomoaki Yatsufusa, Akira Miyoshi, Yuta Shinji, Yi Rong Chen, Yasuyuki Sakai, Yu Chao Liao, Yoshihisa Nou, Shimpei Yamada |
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| Rok vydání: | 2021 |
| Předmět: |
Materials science
010304 chemical physics Laminar flame speed General Chemical Engineering General Physics and Astronomy Energy Engineering and Power Technology Thermodynamics Laminar flow CHEMKIN 02 engineering and technology General Chemistry Flame speed Combustion 01 natural sciences chemistry.chemical_compound Fuel Technology 020401 chemical engineering chemistry 0103 physical sciences Combustor 0204 chemical engineering Nonane Shock tube |
| Zdroj: | Combustion and Flame. 227:283-295 |
| ISSN: | 0010-2180 |
| DOI: | 10.1016/j.combustflame.2020.12.043 |
| Popis: | Ignition delay times (IDTs) and laminar flame speeds (SL) of C9H20 (nonane) isomers are systematically investigated. IDTs of normal nonane (n-C9), 2-methyloctane (2mC8), 2,4-dimethylheptane (24mC7), and 2,2,4,4-tetramethylpentane (2244mC5) are experimetally obtained by a shock tube facility and numerically simulated by a chemkin 0-D reactor model. Further, laminar flame speeds (SL) of n-C9 and 2244mC5 are measured by spherical expanding flames in a constant-temperature, constant-pressure dual-chamber cruciform burner over a wide range of the equivalence ratio (Φ = 0.7–1.4), which are used to compare with numerically simulated results obtained by chemkin 1-D flame speed model. Detailed reaction mechanisms of KUCRS, LLNL and JetSurF ver.02 are used for numerical simulations. It is found that experimental IDTs increase with the number of methyl branches, especially in low-temperature and negative temperature coefficient (NTC) regions, where the increase of IDT with the number of methyl branches are well predicted by KUCRS. We also find that the measured values of SL of highly branched 2244mC5 are smaller than those of n-C9 at all values of Φ studied, of which measured SL data are successfully reproduced by the 1-D flame speed model with KUCRS. These results are important to our understanding of reaction characteristics for highly branched nonane isomers and for the designing of optimal alternative fuels in internal combustion engines. |
| Databáze: | OpenAIRE |
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