The properties of five highly conducting salts: (TMTSF)2X,X= Pf−6, AsF−6, SbF−6, BF−4 and NO-3, derived from tetramethyltetraselenafulvalene (TMTSF)
Autor: | Claus Schelde Jacobsen, H. J. Pedersen, Niels Thorup, Kell Mortensen, Klaus Bechgaard |
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Rok vydání: | 1993 |
Předmět: | |
Zdroj: | Solid State Communications. 88:963-969 |
ISSN: | 0038-1098 |
DOI: | 10.1016/0038-1098(93)90278-u |
Popis: | The properties of five new highly conducting salts of TMTSF, (TMTSF)2X, X = PF-6, AsF-6, SbF-6, BF-4 and NO-3 are reported. The measurements include d.c. and m.w. conductivity, thermopower, optical reflectivity, magnetic susceptibility and 19F-NMR. Preliminary structural data indicate uniform donor stacks. Metal to insulator transitions in four materials occur below 20 K, where specific conductivities higher than 105 (Ω-cm)-1 are observed for two salts (X = PF-6 and NO-3). |
Databáze: | OpenAIRE |
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