Catalytic Synthesis of Cyclic and Linear Germoxanes Mediated by an Iron Complex

Autor:	Ryosuke Tada, Kozo Fukumoto, Masahiro Kamitani, Masumi Itazaki, Hiroshi Nakazawa
Rok vydání:	2012
Předmět:	chemistry.chemical_classification Organic Chemistry Inorganic chemistry Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Dimethylformamide Iron complex Thermal reaction Physical and Theoretical Chemistry Carbene Iron catalyst Alkyl
Zdroj:	Organometallics. 31:2957-2960
ISSN:	1520-6041 0276-7333
Popis:	Six-membered cyclic germoxanes (R2GeO)3 were selectively prepared via the thermal reaction of (alkyl)2GeH2 in dimethylformamide (DMF). Linear metallagermoxanes with an E–O–Ge–O–E backbone (E = Si, Ge, Sn) were prepared by the reaction of Ph2GeH2 with R3EH in DMF. Their cyclic and linear germoxane formations were achieved using an iron catalyst, (η(5)-C5H5)Fe(CO)2Me. An iron carbene complex was proposed to be an intermediate in the catalytic reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::cb98047560b7743a3e28d7b11dd3e707 https://doi.org/10.1021/om3001845 Zobrazit plný text záznamu