Effects of curing systems on the mechanical and chemical ageing resistance properties of gasket compounds based on ethylene-propylene-diene-termonomer rubber in a simulated fuel cell environment
| Autor: | Bismark Mensah, Jou-Hyeon Ahn, Gopi Sathi Shibulal, Yong Hwan Yoo, Changwoon Nah, Bo Ki Hong, Byeong-Heon Jeong, Seung Gyeom Kim |
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| Rok vydání: | 2015 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Vulcanization Energy Engineering and Power Technology Compression set Ethylene propylene rubber Condensed Matter Physics law.invention Fuel Technology Chemical engineering Natural rubber law visual_art Polymer chemistry visual_art.visual_art_medium Chemical stability Fourier transform infrared spectroscopy Curing (chemistry) Chemical decomposition |
| Zdroj: | International Journal of Hydrogen Energy. 40:10627-10635 |
| ISSN: | 0360-3199 |
| Popis: | Ethylene-propylene-diene-termonomer (EPDM) rubber based fuel cell gasket compounds have been designed and explored the effects of various vulcanization systems on different properties. Three types of sulphur-accelerated vulcanization systems such as conventional vulcanization (con), semi-efficient vulcanization (sev) and efficient vulcanization (ev) and also a peroxide vulcanization system were employed in this study. The curing characteristics, tensile, hardness and compression set properties of the cured compounds were evaluated. The crosslink density was assessed by equilibrium swelling method in dodecane. The chemical stability of the cured EPDM compounds was also evaluated through an accelerated durability test (ADT) using a solution (1 M H2SO4 + 10 ppm HF) very close to the fuel cell atmosphere. Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), energy dispersive X-ray spectroscopy (EDX) and scanning electron microscopy (SEM) were employed to investigate the chemical and physical changes of the cured EPDM compounds before and after exposure to the ADT solution over time. The results indicate that the EPDM compounds cured with peroxide exhibit the highest crosslink density with lowest compression set value at both room temperature and at elevated temperature. The FTIR and the corresponding SEM results show no significant chemical degradation of the peroxide cured EPDM compounds due to ADT ageing. |
| Databáze: | OpenAIRE |
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