Phenylalanine derivatives containing an acyl residue of the stereoisomeric N-[di(ethylenimino)(thio)phosphoryl]-4-aminocyclohexanecarboxylic acids

Autor:	I. L. Knunyants, K. I. Karpayichyus, L. A. Patotskene
Rok vydání:	1978
Předmět:	inorganic chemicals Acyl residue Chemistry Stereochemistry Thio Phenylalanine General Chemistry Ethyl ester environment and public health Phenylalanine derivatives Acylation enzymes and coenzymes (carbohydrates) bacteria heterocyclic compounds
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:790-795
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00925309
Popis:	1. The most convenient method for the acylation of phenylalanine by N-acyl derivatives of aminocyclohexanecarboxylic acid (ACHCA) employs mixed anhydrides, and protection by the N-carbobenzoxy group is the most convenient method for the blocking of the amino group in ACHCA. 2. The ethyl esters of N-[dichloro(thio)phosphoryl]-cis-4-ACHC-DL-phenylalanine, N-[dichlpro(thio)-phosphoryl]-trans-4-ACHC-DL-phenylalanine, N-[di(ethylenimino)(thio)phosphoryl]-cis-4-ACHC-DL-phenylalanine, and N-[di(ethylenimino)(thio)phosphoryl]-trans-4-ACHC-DL-phenylananine, as well as the Na salts of N-[di(ethylenimino)(thio)phosphoryl]-cis-4-ACHC-DL-phenylalanine and N-[di(ethylenimino)(thio)-phosphoryl]-trans-4-ACHC-DL-phenylalanine, have been synthesized.
Databáze:	OpenAIRE
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