Reversible cyclisation reactions to form ruthenafurans: X-ray crystal structure of [Ru(CO){C(Ph)OC(OEt)CH}Cl(PMe2Ph)2]
| Autor: | Amanda J. Reid, Paul D. Morran, Martin P. Waugh, Roger J. Mawby, Colin D. Reynolds, Fritjof C. F. Körber |
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| Rok vydání: | 1995 |
| Předmět: | |
| Zdroj: | J. Chem. Soc., Chem. Commun.. :941-942 |
| ISSN: | 0022-4936 |
| DOI: | 10.1039/c39950000941 |
| Popis: | Ruthenafurans [R[graphic omitted]H}ClL2](L = PMe2Ph, R = CHCHOEt, CHCHCMe3, Me or Ph; L = PMe3, R = CHCHOEt or CHCHPh) can be formed reversibly from [Ru(CO)2RClL2] and EtOCCH: the rate-determining forward step involves the formation of the intermediate [Ru(CO)(COR)ClL2], which can be trapped when the reverse reaction occurs in the presence of Me3CNC. |
| Databáze: | OpenAIRE |
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